Nashville, Tenn. ? George and Tammy are there. So are Johnny and Hank, and Waylon and Willie.

But a ranking of the top 100 songs in country music history is bound to contain a few surprises, and the new one by Country Music Television is no exception.

Is Tammy Wynette’s 1968 classic “Stand by Your Man” truly the best country song of all time? Should Garth Brooks’ “Friends in Low Places” rank that high (No. 6)? Is the Eagles’ “Desperado” really a country song? And where’s Merle Haggard’s “The Fightin’ Side of Me”?

“Everyone has personal favorites that didn’t make the list,” said Kaye Zusmann, CMT’s vice president of program development and production. “Everyone will look and say, ‘How can that not make it on there?”‘

The list was revealed in a Wednesday concert on the eve of Nashville’s annual Fan Fair country music festival. The four-hour documentary will be broadcast at 3 p.m. Sunday on CMT.

The process began last summer when CMT asked music critics, historians and journalists to identify the genre’s greatest songs. They came up with 600 titles.

That list went to voting members of the Country Music Assn., which consists of songwriters, musicians, singers and other industry insiders, who whittled it down to 100 songs and ranked them.

The criteria was loose. Statistics such as weeks on the chart or total sales didn’t matter, Zusmann said, only the “emotional, visceral connection people have to a song.”

That figured heavily in the top choice, “Stand by Your Man,” Wynette’s plea to women to forgive their wayward men.

George Jones, Wynette’s husband from 1969 to 1975 and duet partner, said Tuesday that “Stand by Your Man” touched both men and women, especially with the Vietnam War pulling couples apart.

“When you’re away from home, it enters your mind, you know,” he said. “You hope she’s not fooling around, and you’re missing home.”

Jones, who has the No. 2 song on the list with “He Stopped Loving Her Today,” said Wynette’s signature song “belongs where it is.”

Rounding out the CMT top 10, in order, after Wynette and Jones: Patsy Cline’s “Crazy,” Johnny Cash’s “Ring of Fire,” Hank Williams’ “Your Cheatin’ Heart,” Brooks’ “Friends in Low Places,” Cline’s “I Fall to Pieces,” Glen Campbell’s “Galveston,” Charlie Rich’s “Behind Closed Doors,” and Waylon Jennings’ and Willie Nelson’s “Mommas Don’t Let Your Babies Grow Up to Be Cowboys.”